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The molar volume (cm^3 mol^-1) of a binary liquid mixture at T and P is given by: V=120 x1 70 x2 (15 x1 8 x2) x1 x2 (a) Find expressions for the partial molar volumes of species 1 and 2 at T and P. (b) Show that when these expressions are combined in accord with Eq. (11.11) the given equation for V is recovered. (c) Show that these expressions satisfy Eq. (11.14), the Gibbs/Duhem equation. (d) Show that (d V̅1 / d x1)τ1=1=(d V̅2 / d x1)x1=0=0 (c) Plot values of V, V̅1, and V̅2 calculated by the
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