Synthesis and Structural Investigation of Zr (BH4)4
Aug 31, 2012 · Zirconium tetraborohydride, Zr(BH4)4, was synthesized by a metathesis reaction between LiBH4 and ZrCl4 using high-energy ball milling. Initially, a white powder was …
Synthesis and thermal stability of Zr(BH4)4 and Zr(BD4)4 …
Aug 1, 2009 · Zirconium tetrahydroborate Zr(BH 4) 4 and its deuteride compound Zr(BD 4) 4 were successfully synthesized by mechanochemical reaction between NaBH 4 or NaBD 4 and ZrCl …
Structure of zirconium tetrahydroborate Zr(BH4)4: A molecular …
Jan 24, 2017 · In the work the structural and thermodynamic characteristics of zirconium tetrahydroborate Zr (BH 4) 4 are considered. The initial compound organized in a cubic lattice …
Synthesis and hydrogen storage property tuning of Zr(BH4)4…
Oct 11, 2018 · Recently, we successfully synthesized zirconium borohydride octaammoniate, Zr (BH 4) 4 ·8NH 3, with the highest coordination number of NH 3 groups among all the reported …
Structural and thermodynamic investigations of Zr(BH4)4 and Hf(BH4)4 …
Jan 12, 2024 · The borohydrides of zirconium (Zr (BH 4) 4) and hafnium (Hf (BH 4) 4) have been prepared by solid state metatheses. The crystal structures were determined slightly below their …
Synthesis and Structural Investigation of Zr(BH4)4 - Semantic …
Zirconium tetraborohydride, Zr (BH4)4, was synthesized by a metathesis reaction between LiBH4 and ZrCl4 using high-energy ball milling. Initially, a white powder was produced, and during …
Synthesis and Structural Investigation of Zr (BH4) (4)
Sep 27, 2012 · Zirconium tetraborohydride, Zr(BH4)(4), was synthesized by a metathesis reaction between LiBH4 and ZrCl4 using high-energy ball milling.
Electron-diffraction investigation of zirconium tetraborohydride, Zr(BH4)4
Molecular Structures of Two Metal Tetrakis(tetrahydroborates), Zr(BH4)4 and U(BH4)4: Equilibrium Conformations and Barriers to Internal Rotation of the Triply Bridging BH4 Groups. …
Synthesis and Structural Investigation of Zr(BH4)4,The Journal of ...
Zirconium tetraborohydride, Zr (BH4)4, was synthesized by a metathesis reaction between LiBH4 and ZrCl4 using high-energy ball milling. Initially, a white powder was produced, and during …
Molecular Structures of Two Metal Tetrakis(tetrahydroborates), Zr(BH4)4 ...
Nov 14, 2002 · The molecular structures and equilibrium conformations of Zr(BH4)4 and U(BH4)4 have been determined by DFT calculations, gas electron diffraction, and matrix isolation IR …