
Engineering β -ketoamine covalent organic frameworks for
Feb 3, 2023 · The TpBD-COF, TpBpy-2-COF, and TpBpy-COF, were synthesized by the reported methods with modification and exfoliated to COFs-NS by “top-down” route.
TpBD COF@ZnIn2S4 nanosheets: A novel S-scheme …
Aug 5, 2023 · Herein, we report, for the first time, on the construction of a heterojunction consisting of core-shell structured 1,3,5-triformylphloroglucinol (Tp) and 4,4′ …
Sequential Pore Wall Modification in a Covalent Organic …
Nov 16, 2015 · Here we describe the synthesis and postsynthetic modification of the stable β-ketoenamine TpBD(NH 2) 2 covalent organic framework (COF), having primary amine groups …
Preparation of hollow tubular TpBD COF and pod-like ZIF-8/H-TpBD COF …
Nov 29, 2021 · By sacrificing a porous anodic aluminum oxide (AAO) membrane as a template, hollow tubular TpBD (H-TpBD) covalent organic framework (COF) tubes were synthesized in …
Hydrogen-bonding and π-π interaction promoted solution
Dec 11, 2023 · In this study, we develop a convenient top-down process for fabricating solution-processable covalent organic frameworks by introducing intermolecular hydrogen bonding and …
Chemically Stable Multilayered Covalent Organic Nanosheets from ...
Oct 29, 2013 · A series of five thermally and chemically stable functionalized covalent organic frameworks (COFs), namely, TpPa-NO 2, TpPa-F 4, TpBD-(NO 2) 2, TpBD-Me 2, and TpBD …
Carbon-to-nitrogen atom transmutations in a covalent organic …
Jan 3, 2025 · In this work, four carbon-to-nitrogen atom transmutations in an established COF, TpBD-COF, lead to the design of a new COF, TpBmd-COF, transforming the photocatalytic …
Lewis acid‐driven interlayer shifting in sub‐nm 2D covalent organic ...
3 days ago · (D) 13 C SSNMR spectrum signifying the different signals for the methyl group of the TPBD(Me) 2-Y and TPBD(Me) 2-C COF powders. To probe into the mechanism of Lewis-acid …
Screening and preparation of functionalized TpBD-COFs for CO
Jan 5, 2025 · Grand canonical Monte Carlo (GCMC) method was used to simulate the adsorption capacity of CO 2 over X-TpBD-COFs (X=–NO 2, –CN, −Br, –CH 2 NH 2, –CH 3, –OCH 3).
Designing Local Electron Delocalization in 2D Covalent Organic ...
Feb 20, 2024 · Herein, TPBD covalent organic frameworks (COFs) with controlled electron-delocalization characteristics (denoted as TPBD- R -COF, R = H, F, CN, and NO 2) were …