Apr 10, 2023 · We selected an as-synthesized COF-301 (termed COF-301-S) to prove the single crystallinity and resolve the atomic structure with single-crystal X-ray diffraction (XRD; …

Jul 14, 2023 · We show that symmetry-asymmetry tautomerisation from diiminol to iminol/cis-ketoenamine can be stabilised and switched in a crystalline, porous, and dynamic 3D COF …

Using accurate quantum mechanical (QM) methods, we studied the H2 binding energy to 48 compounds based on various metalated analogues of five common linkers for covalent organic …

Jan 30, 2019 · Based on the results of PXRD patterns and 1 H NMR spectra, the COF-320-to-COF-300 transformation was successfully achieved, and an efficiency as high as 89% was …

Jan 24, 2025 · As a result, COF-301-PL demonstrates excellent fluidity and porosity at room temperature. The intrinsic flexibility of COF-301, derived from its distorted tetrahedral building …

Jul 6, 2018 · Single crystals of COFs amenable to x-ray diffraction characterization have not been reported. Here, we developed a general procedure to grow large single crystals of three …

Jan 25, 2023 · Here, a highly crystalline three-dimensional hydroxylated covalent organic frameworks (denoted by COF-301) with tetra (4-anilyl)methane (TAM) and 2,5 …

Mar 27, 2024 · Three-dimensional single-crystal COF-301 (SCOF-301) with an intramolecular H-bond-induced excited-state intramolecular proton-transfer effect is selected as a proof-of …

Feb 27, 2020 · Two reported three-dimensional covalent organic frameworks (3D-COFs), COF-300 and COF-301, which have hierarchical porous structures and large pore volumes, were …

Covalent organic frameworks (COFs) have emerged as highly crystalline porous organic materials and proven to be potential candidates for various interesting applications, such as gas …