Apr 13, 2007 · Atomic connectivity and structure of crystalline products of COF-102 (A), COF-105 (B), and COF-108 (C), based on PXRD and modeling. Hydrogen atoms are omitted for clarity.

Abstract: Three-dimensional covalent organic frameworks (3D COFs) were synthesized by targeting two nets based on triangular and tetrahedral nodes: ctn and bor.

Dec 18, 2018 · Most early 3D COF structures were formed utilizing boron–oxygen (B–O) linkages. The first 3D COFs, COF-102, COF-103, COF-105, and COF-108 were synthesized from the …

In the case of COF-102, a 3D structure prepared by the auto-condensation of tetra (4-dihydroxyborylphenyl)methane (TBPM) (Scheme 4), an H 2 maximum adsorption capacity of …

The organometallic host–guest chemistry of porous covalent organic frameworks is explored by vapour phase infiltration of volatile organometallic precursors; namely, [Fe (η5-C5H5)2], [Co …

Jan 14, 2014 · Here we elaborate this approach by demonstrating that monofunctional arylboronic acids serve as effective truncation/functionalization agents for COF-102, a boroxine-linked 3D …

Mar 5, 2024 · We report a rapid, room-temperature mechanochemical synthesis of 2- and 3-dimensional boroxine covalent organic frameworks (COFs), enabled by using …

We demonstrate a tandem truncation–functionalization strategy using the 3D covalent organic framework, COF-102. Allyl groups incorporated within the pore walls were subjected to …

Jan 5, 2015 · The methane uptakes of six double halogen substituted covalent organic frameworks (COFs) based on COF-102 were simulated with grand canonical Monte Carlo …

Jan 15, 2021 · The Pd nanoparticles modified COF-102 possessed narrow pore size distribution (2.4 ± 0.5 nm) without any larger metallic aggregation even under 30 wt% Pd loadings, …