Feb 25, 2021 · Several 2D MOFs are suitable for exfoliation as ultrathin nanosheets similar to graphene and other 2D materials, making these layered structures useful and unique for various technological applications. Furthermore, these layered structures have fascinating topological networks and entanglements.

Mar 1, 2024 · 2D conjugated metal–organic frameworks (2D -MOFs) have emerged as a class of graphene-like materials with fully π-conjugated aromatic structures. Their unique structural characteristics provide abundant physiochemical features, including regular nanochannels, high electrical conductivity, and customizable band gaps.

Aug 28, 2021 · This review presents a relatively comprehensive summary of the design & synthesis and applications of two-dimensional MOF over the past few years. Furthermore, the opportunities and challenges have been discussed to supply a promising prospect to this field.

Jan 19, 2021 · Typically, two-dimensional conjugated MOFs (2D c-MOFs) are a novel class of layer-stacked MOFs with in-plane extended π-conjugation that exhibit unique properties such as intrinsic porosity, crystallinity, stability, and electrical conductivity as well as tailorable band gaps.

Sep 14, 2022 · Here, we report the synthesis of two-dimensional (2D) layered metal–organic framework (MOF) nanoparticle (NP) superstructures via an ice-templating strategy. MOF NP monolayers and bilayers can be obtained by regulating the concentration of colloidal MOF NPs without any external fields during self-assembly.

3 days ago · Different from its counterpart 2D c-MOF Ni-HHTQ and Cu-HHTP, Cu-HHTQ features stronger electronegativity, stronger conjugated degree and excellent electronic structure by analyzing EA-DOS ...

Jul 4, 2018 · Two-dimensional (2D) metal–organic framework (MOF) nanosheets are attracting increasing research attention due to their unique properties originating from their ultrathin thickness, large surface area and high surface-to-volume atom ratios.

Jan 11, 2023 · In this review, we provide a synopsis of the recent progress in the field of 2D MOFs for sensor applications. Initially, the properties and synthesis techniques of 2D MOFs are briefly outlined with examples. Further, electrochemical and optical biosensors based on 2D MOFs are summarized, and the associated challenges are outlined. 1. Introduction.

May 2, 2022 · At present, 2D-MOF materials integrate ultrathin thickness, large surface-to-volume ratio, variety of ligands, permanent porous structure, and highly designability, which has steadily exhibited great potential in nanomedicine and biology.

Apr 14, 2021 · This review provides an overview of different aspects of 2D MOF layered architectures such as topology, interpenetration, structural transformations, properties, and applications.