
Untwisted restacking of two-dimensional metal-organic ... - Nature
Jul 2, 2019 · The untwisted Zr-BTB-FA nanosheets coated column showed significant separation performance with excellent selectivity for six groups of substituted aromatic isomers including ethylbenzene,...
Zr-BTB nanosheets assist in optimizing the structure of forward …
Jul 1, 2024 · Oligo-layer Zr-BTB nanosheets were loaded onto the support layer surface by pumping filtration to form a nanosheet interlayer, which modulated the amine monomer attachment and diffusion behavior through spatial site resistance and interactions, resulting in a thin and dense intact separation layer.
Porous Zirconium Metal–Organic Framework Constructed from 2D …
Jul 7, 2014 · The Zr 6 clusters were linked by BTB ligands to generate a 2D network of kgd topology. The interpenetrations among the 2D networks gave rise to a 3D porous framework, which represents the first Zr MOF constructed from 2D → 3D interpenetration.
Rapid microwave synthesis of PCN-134-2D for singlet oxygen …
Sep 1, 2022 · Rapid preparation of Zr-BTB nanosheets and PCN-134-2D by microwave-assisted solvothermal method. Photodegradation efficiency for RAN reached to 93.1%. PCN-134-2D exhibited enhanced photocatalytic performance due to the augmentation of the TCPP/BTB ratio.
Active mechanisorption driven by pumping cassettes | Science
Oct 21, 2021 · We selected a robust, ultrathin MOF nanosheet composed of Zr-BTB (46, 47), where BTB stands for 4,4′,4′′-benzene-1,3,5-triyl-tris(benzoic acid) , as an ideal platform on which to graft AMPs.
Thermodynamically Guided Synthesis of Mixed-Linker Zr-MOFs …
May 6, 2016 · Guided by thermodynamics, we have synthesized two mixed-linker zirconium-based metal–organic frameworks (Zr-MOFs), namely, PCN-133 and PCN-134.
Photosensitizer‐Anchored 2D MOF Nanosheets as Highly Stable …
Apr 9, 2019 · An ultrathin MOF nanosheet-based material, Zr-BTB (BTB = 1,3,5-tris (4-carboxyphenyl)benzene), is initially constructed by connecting Zr 6 -clusters with the tritopic carboxylate linker.
Construction of porous 2D MOF nanosheets for rapid and selective ...
Feb 3, 2021 · These 2D-MOF nanosheets are ultrathin, have large surface area and high water stability and can selectively adsorb cationic dyes, rhodamine B (RhB) and methylene blue (MLB), from aqueous solutions, with removal rates of nearly 100% within 10 min.
Fabrication of Zr-BTB@TiO2@Fe3O4 Nanosheets via Combining …
Oct 20, 2022 · The Zr-BTB@TiO 2 @Fe 3 O 4 nanosheets exhibit outstanding enrichment ability with high sensitivity (0.4 fmol μL –1), superior selectivity (β-casein/Cyt C molar ratio 1:1000), and ideal batch-to-batch reusability (5 times).
Zr-BTB nanosheets assist in optimizing the structure of forward …
Jul 1, 2024 · Oligo-layer Zr-BTB nanosheets were loaded onto the support layer surface by pumping filtration to form a nanosheet interlayer, which modulated the amine monomer attachment and diffusion behavior through spatial site resistance and interactions, resulting in a thin and dense intact separation layer.
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