
Uranium borohydride - Wikipedia
Uranium borohydride is the inorganic compound with the empirical formula U(BH 4) 4. Two polymeric forms are known, as well as a monomeric derivative that exists in the gas phase. …
spectroscopic properties of U(BH4)4 because of their high site symmetry at low temperatures, sim ple crystallographic structure, and the substitu tional nature (vide infra) of the U(BH4)4/Hf, …
14-Coordinate uranium(IV). Structure of uranium borohydride by …
Optical and magnetic resonance spectra of inorganic molecular crystals-uranium borohydride [U(BH4)4] in hafnium borohydride [Hf(BH4)4]. The Journal of Chemical Physics 1973, 59 (4) , …
Preparation and crystal structure of uranium(IV) borohydride …
May 1, 2002 · Derivatives of U(BH4)4 and its Lewis base adducts; synthesis of monocyclopentadienyl- and hydride-uranium(IV) complexes: (η-C5H5)U(BH4)3 and …
The structure of U(BH4)4 has been refined by a single-crystal neutron diffraction study. The X-ray structure (tetragonal, P4~2~2 (P412~2), a = 7.49 (1) A, c = 13.24 (1) A, Z = 4, pcalcd 2.66 …
Photochemistry of U (BH4)4 and U (BD4)4 - ScienceDirect
Jan 1, 1979 · The volatility of U(BH4)4 and U(BD4)4, their structural complexity and the extensive spectroscopic data avail- able have led us to explore some aspects of the UV and IR …
Derivatives of U(BH4)4 and its Lewis base adducts; synthesis of ...
Jul 19, 1988 · In this paper, we suggest an explanation for this structural feature, which can be related to the reactivity of the borohydride group. We also present and discuss the results of …
U(BH4)4 radical - NIST Chemistry WebBook
U(BH4)4 radical. Formula: B 4 H 16 U; Molecular weight: 297.400; CAS Registry Number: 102630-71-7; Information on this page: Reaction thermochemistry data; Ion clustering data; …
mp-27350: U(BH4)4 (tetragonal, P4_32_12, 96) - Materials Project
U (BH4)4 crystallizes in the tetragonal P4_32_12 space group. The structure is three-dimensional. U4+ is bonded in a 10-coordinate geometry to fourteen H+0.50+ atoms. There are a spread of …
U(BH4)4 (Uranium borohydride) molar mass - Chemical Portal
Uranium borohydride is a solid green in color, with a polymeric form that converts to a gaseous monomeric derivative at mild temperatures. To calculate molar mass of a chemical compound …