
Biocompatible 2D Cu-TCPP Nanosheets Derived from Cu
Feb 7, 2022 · Two-dimensional (2D) metal–organic frameworks (MOFs) could serve as multifunctional nanoplatforms to load small-molecule drugs and enzyme-mimicking nanoparticles (NPs) with a high efficiency for combined cancer therapy.
Synthesis, characterization, and photocurrent generation of a new ...
Tetrakis (4-carboxyphenyl)porphyrin (TCPP) is a prototypical chromophore which has been used as a building block in MOFs and photovoltaic applications. 22,23 In the TCPP based MOFs the formed C–O–metal bond between TCPP and metal node could act as the electron transfer channel, facilitating the electron injection from excited porphyrin units to ...
Integration of P84 and porphyrin–based 2D MOFs (M−TCPP, M = Zn, Cu…
Feb 1, 2022 · Herein, a series of tetrakis(4-carboxyphenyl)porphyrin (abbreviation: TCPP) based metal–organic frameworks (MOFs, M−TCPP (M=Zn, Cu, Co, Ni)) have been synthesized in the form of two–dimensional nanosheets, which were then used as thin fillers in P84 matrix to fabricate M−TCPP/P84 MMMs for the OSN application.
Anisotropic flexibility and rigidification in a TPE-based Zr ... - Nature
Sep 2, 2023 · Tetraphenylethylene (TPE)-based ligands are appealing for constructing metal-organic frameworks (MOFs) with new functions and responsiveness. Here, we report a non-interpenetrated TPE-based scu...
Direct Electrochemical Synthesis of Metal-Organic Frameworks: Cu
Nov 24, 2023 · In this research, the MOFs Cu 3 (BTC) 2 and Cu (TCPP) were electrochemically synthesized via anodic dissolution of Cu thin films and well-defined Cu-based microstructures as the only Cu source in the partial electrochemical synthesis.
Economically Scalable Cu‐based MOFs: Vital Role of Structural …
Dec 4, 2024 · A scalable production of Cu-triazole MOF through a facile and economical route is demonstrated. Providing hydrophilic pores with open-metal Cu-sites, the framework is highly selective to water adsorption from an azeotropic mixture of water-ethanol.
Recent advances in Cu(II)/Cu(I)-MOFs based nano-platforms for ...
Dec 1, 2021 · Metal-organic frameworks (MOFs) are organic-inorganic hybrid crystalline porous material. An overview about recent progress in copper based MOFs in developing nano-medicines given. Application of copper based MOFs for chemodynamic and photodynamic therapy discussed.
A series of novel Cu-based MOFs: syntheses, structural diversity ...
May 26, 2022 · MOFs 1–3 possess 3D networks which consist of three different types of Cu clusters {Cu 2 O 2 (OCO) 4}, {Cu 2 O 2 N 4 (OCO) 2} and {Cu 4 O 10 (OCO) 4}, respectively. MOFs 1–3 efficiently catalyze the oxidation of cycloalkanes under mild conditions.
Tetraphenylethylene (TPE)-based ligands are appealing for constructing metal-organic frameworks (MOFs) with new functions and responsiveness. Here, we report a non-interpenetrated TPE-based scu...
Porous Cu-based metal organic framework (Cu-MOF) for highly …
Jun 1, 2023 · In this study, copper based metal organic frame work (Cu-MOF) was synthesized by using different solvents i. e. H 2O, Dimethylformamide (DMF) and DMF + C2 H 5 OH + H 2O solutions at various temperatures.