The name reaction is a type of shorthand that avoids the need to give a lengthier explanation of the features of a particular transformation of interest. Mentioning the name reaction allows a knowledgeable listener to bring to mind the possible substrates, reaction conditions, or mechanistic details.

Name Reactions. Further Information Literature. Related Reactions Schmidt Reaction. Curtius Rearrangement. The Curtius Rearrangement is the thermal decomposition of carboxylic azides to produce an isocyanate. These intermediates may be isolated, or their corresponding reaction or hydrolysis products may be obtained.

Kolbe-Schmitt Reaction. A base-promoted carboxylation of phenols that allows the synthesis of salicylic acid derivatives.

Reactions >> Name Reactions. Further Information Literature. Related Reactions Wurtz Reaction. Wurtz-Fittig Reaction. This reaction allows the alkylation of aryl halides. The more reactive alkyl halide forms an organosodium first, and this reacts as a nucleophile with an aryl halide as the electrophile. Excess alkyl halide and sodium may be ...

Contains information on the most important Name Reactions and keywords for the field of organic synthesis. Organic Synthesis Search A graphical index of bond types provides links to search for specific transformations of interest and locate examples to use in solving synthetic problems.

Schmidt Reaction. The acid-catalysed reaction of hydrogen azide with electrophiles, such as carbonyl compounds, tertiary alcohols or alkenes. After a rearrangement and extrusion of N 2, amines, nitriles, amides or imines are produced.

Reactions >> Name Reactions. Further Information Literature. Related Reactions Wurtz-Fittig Reaction Synthesis of alkanes. Wurtz Reaction. The Wurtz Coupling is one of the oldest organic reactions, and produces the simple dimer derived from two equivalents of alkyl halide. The intramolecular version of the reaction has also found application in ...

Mechanism of the Cannizzaro Reaction. An interesting variant, the Crossed Cannizzaro Reaction, uses formaldehyde as reducing agent: At the present time, various oxidizing and reducing agents can be used to carry out such conversions (with higher yields), so that today the Cannizzaro Reaction has limited synthetic utility except for the abovementioned conversion of α …

Mechanism of the Finkelstein Reaction. The equilibrium position of the reaction depends on the nucleophilicity of the anion, whether a good leaving group is present, and whether one anion is better stabilized than the other in a given solvent (see Nucleophilic Substitution).For example, reactions with KF will thus lead cleanly to fluoroalkanes, because fluoride is such a …

Mechanism of the Sandmeyer Reaction. Recent Literature. Catalytic Sandmeyer Bromination I. P. Beletskaya, A. S. Sigeev, A. S. Peregudov, P. V. Petrovskii, Synthesis, 2007, 2534-2538. Halo- and Azidodediazoniation of Arenediazonium Tetrafluoroborates with Trimethylsilyl Halides and Trimethylsilyl Azide and Sandmeyer-Type Bromodediazoniation with …