
A Sodium-Based Phosphonates Metal–Organic Framework with …
Nov 7, 2023 · A novel alkali metal-based metal–organic framework (Na-MOF) has been successfully prepared under solvothermal conditions using tetrakis(4-phosphonatophenyl)ethylene (H 8 TPE) as a ligand and NaOH as a metal source.
Nanopalladium-Decorated Sn-Na MOF Catalyst for Upgrading …
Jul 6, 2023 · The present study explores the solvothermal synthesis of the Sn-Na MOF composed of stannatranone cages interconnected through Na bridges. The MOF was used as a catalytic support to hold palladium nanoparticles.
Metal-organic framework functionalization and design …
Jul 26, 2019 · Metal-organic frameworks (MOFs) are a class of porous materials with unprecedented chemical and structural tunability. Their synthetic versatility, long-range order, and rich host–guest...
Nano-sized metal-organic frameworks: Synthesis and applications
Aug 15, 2020 · In this review, we first summarize the synthetic strategies of uniform and monodisperse nanoMOFs, and then the intrinsic size-dependent properties towards the most important applications are highlighted as well.
Highly Dense N–N-Bridged Dinitramino Bistriazole ... - ACS …
Apr 10, 2024 · Herein, based on the nitrogen-rich N,N′-([4,4′-bi(1,2,4-triazole)]-3,3′-dial)dinitramide (H 2 BDNBT) energetic ligand, two new environmentally benign E-MOFs including potassium [K 2 BDNBT] n (K-MOF) and sodium [Na 2 BDNBT] n (Na-MOF) have been introduced and characterized by NMR, IR, TGA-DSC, ICP-MS, PXRD, elemental analyses, and SCXRD.
Sodiophilic Current Collectors Based on MOF‐Derived …
Sep 20, 2022 · In this work, we demonstrate a facile strategy to construct a robust nucleation buffer layer by applying a Cu-based MOF (Cu-BTC) -derived composite, i.e., copper nanoparticles embedded in carbon framework (denoted as Cu@C), on conventional current collectors.
Electronic band structure engineering of π-d conjugated metal …
5 days ago · As a result, Cu-HHTQ achieves a high discharge voltage at 2.55 V (vs. Na + /Na), a higher stable specific capacity of 208 mAh g −1 at 0.05 A g −1, and long cyclability with the capacity ...
Chemistry – A European Journal
Oct 21, 2024 · Construct metal-organic framework (MOF) strategy to provide three-dimensional coordination bonds network to protect the organic ligands intrinsic Hydrogen bond network.
Na intercalation in Fe-MIL-100 for aqueous Na-ion batteries
May 4, 2017 · Here we report for the first time the feasibility of using metal–organic frameworks (MOFs) as electrodes for aqueous Na-ion batteries. We show that Fe-MIL-100, a known redox-active MOF, is electrochemically active in a Na aqueous electrolyte, under various compositions.
ZnNi(NA) (NA= Nicotinic acid) bimetallic mesoporous MOFs as a …
Mar 1, 2022 · A novel bimetallic ZnNi(NA) (NA = Nicotinic acid) MOF nanomaterials with molar ratios of 3:1; 1:1; and 1:3 are deployed as sensing materials for detection of NH 3, HCHO and C 2 H 5 OH vapours at room temperature. These metal-organic frameworks (MOFs) were synthesized in 3:1 methanol and water solvents at 130 °C by solvothermal method.