Triethyl(silane-d) 97 atom % D; CAS Number: 1631-33-0; Synonyms: Deuterated triethylsilane; Linear Formula: (C2H5)3SiD; find Sigma-Aldrich-489158 MSDS, related peer-reviewed papers, technical documents, similar products & more at Sigma-Aldrich

Jul 8, 2019 · Herein, we report an unprecedented visible-light-mediated metal-free deuteration of silanes using D 2 O as an inexpensive, readily available, and easy to handle deuterium source. A broad range of aryl- and alkyl-substituted silanes were deuterated with high deuterium incorporations and yields.

Feb 18, 2022 · Herein, we report an unprecedented visible-light-mediated metal-free deuteration of silanes using D2O as an inexpensive, readily available, and easy to handle deuterium source. A broad range of aryl- and alkyl-substituted silanes were deuterated with high deuterium incorporations and yields.

Jul 26, 2022 · Chemical vapor deposition-based growth techniques allow flexible design of complementary metal-oxide semiconductor (CMOS) compatible materials. Here, we report the deuterated silicon-rich...

In this paper, we report a novel convenient (60 °C) high-yield synthesis of deuterosilanes from the corresponding hydro-silanes and D2(1 atm) via direct H/D exchange catalyzed by 0.1 1 mol % equivalents of easily accessible simple phosphino-− Pt(0) complexes.

Deuterated silanes refer to compounds obtained by replacing hydrogen in silanes with deuterium isotopes. They can not only be used as important probes for the study of organosilicon chemical mechanisms, but also as general reagents for deuterium labeling.

Oct 1, 2021 · In the Braunschweig infrared laboratory four spectra of deuterated mono–silane SiD 4 have been recorded in the 350–2050 cm − 1 region by use of the Bruker IFS125HR high–resolution Fourier transform infrared spectrometer (Zurich prototype ZP2001 Refs.

Deuterated Silane is a pyrophoric, toxic gas, with a TLV of 5.0 ppm. Deuterated Silane is also used in a variety of research applications to allow determination of hydrogen thermodynamics and incorporation rates. *Additional cylinder sizes and/or valve outlets are available.

Feb 3, 2017 · In this paper, we report a novel convenient (60 °C) high-yield synthesis of deuterosilanes from the corresponding hydrosilanes and D 2 (1 atm) via direct H/D exchange catalyzed by 0.1–1 mol % equivalents of easily accessible simple phosphino-Pt (0) complexes.

Aug 7, 2019 · Herein, we report an unprecedented visible-light-mediated metal-free deuteration of silanes using D 2 O as an inexpensive, readily available, and easy to handle deuterium source. A broad range of aryl- and alkyl-substituted silanes were deuterated with high deuterium incorporations and yields.