
CC3 porous organic cage crystals and membranes for the non …
Aug 15, 2022 · Plasma ammonia synthesis explored over Porous Organic Cage (CC3). CC3 displayed high ammonia yields compared to other microporous crystals. CC3 crystals were translated into a Prototypical Plasma-Membrane Reactor. CC3-membranes dual functionality (adsorber + separator) avoids NH 3 decomposition.
Synthesis of porous organic cage CC3 via solvent ... - ScienceDirect
Feb 1, 2020 · We demonstrate a Humidity Modulated Solvent Evaporation (HMSE) approach to promote the nucleation and growth of CC3 crystals. This approach relies on the gradual evaporation of dichloromethane (solvent) from a diluted concentration of CC3 precursors deposited on aluminum foil.
A Homochiral Porous Organic Cage‐Polymer ... - Wiley Online Library
May 9, 2024 · Here, the authors report the preparation of homochiral porous organic cage (Covalent cage 3 (CC3)- R)-based enantioselective thin-film-composite membranes using polyamide (PA) as the matrix, where fully organic and solvent-processable cage crystals have good compatibility with the polymer scaffold.
Figure 1 shows the PXRD patterns of CC3 crystals synthesized via microwave as a function of synthesis time (experimental details on the microwave synthesis conditions are given in the Supporting Information). All XRD patterns correspond to the common topology of CC3α crystals.
Polycage membranes for precise molecular separation and …
May 30, 2023 · Herein, we report thin film composite membranes prepared by the interfacial polymerization of porous organic cages (POCs) (RCC3 and tren cages). Ultrathin crosslinked polycage selective layers...
XRD patterns of (a) carboxymethyl cellulose, (b) sodium …
Figure 5 shows the XRD patterns of carboxymethyl cellulose, sodium alginate, CaCO 3 , CA3 biocomposite and CC3 biocomposite. The biocomposites, CA3 and CC3 both displayed aragonite crystal...
The XRD patterns of the CC1 (A), CC2 (B), and CC3 (C) samples
In this paper, the hydrothermal method was utilized for the facile synthesis of copper chromite nanoparticles in the absence (abbreviated as CC1) and presence of citric acid (abbreviated as CC2)...
Nanoporous Organic Polymer/Cage Composite Membranes
Dec 6, 2012 · The presence of crystalline CC3 was confirmed by X-ray diffraction (XRD). Area powder XRD studies demonstrated reasonable uniformity of CC3 distribution across the area of the membrane. For PIM-1/nanoCC3 MMMs, SEM showed a particulate structure with an average particle size about 90 nm.
Porous Organic Cage Thin Films and Molecular-Sieving Membranes
Jan 22, 2016 · In the solid state, ASPOC shows a poorly ordered morphology, while CC3, CC13, and FT-RCC3 have a regular octahedral crystal morphology (Figure S2, Supporting Information). X-ray diffraction (XRD) patterns of the cage solids confirmed their crystalline structure (Figure S3, Supporting Information).
(a) XRD patterns of CC3/PIM-1. (b) XRD patterns of IL@CC3/PIM …
Herein, we adopted the cocrystallization strategy for fabricating gas separation membranes. We prepared membranes from a series of [4+6] imine cage pairs, which vary in cavity sizes and include...