
What are the differences and similarities between an aliphatic and …
Sep 8, 2016 · Aliphatic compounds . Aliphatic compounds are hydrocarbons (wiki, compounds containing only $\ce{C}$ and $\ce{H}$) which are not aromatic. An example would be hexane . Alicyclic compounds . Alicyclic compounds are aliphatic compounds that contain one or more rings. An example would be cyclohexene . Gallery
organic chemistry - Where does the name ‘aliphatic’ come from ...
Funny thing is, "aliphatic" also means "producing fats". Goldbook says: aliphatic compounds. Acyclic or cyclic, saturated or unsaturated carbon compounds, excluding aromatic compounds. Some definitions exclude alicyclic compounds from the list of aliphatic compounds, but IUPAC doesn't agree, so. Note that aliphatic compounds can be saturated or ...
Aromatic and aliphatic amines - Chemistry Stack Exchange
Jul 29, 2017 · The benzyl group is a common protecting group for amines, and can be removed via hydrogenation with a palladium catalyst. As for the basicity of the nitrogen, it would be most similar to an aliphatic amine.
What is an aromatic alcohol? - Chemistry Stack Exchange
Jun 13, 2018 · $\begingroup$ Sometimes phenols (OH group connected to the aromatic ring) are not considered to be alcohols, basically because they are much more acidic than aliphatic alcohols. When you use such a convention, aromatic alcohols are those in which you have an aromatic ring and a hydroxyl group connected to a sp3 carbon.
organic chemistry - What is the order of basicity of amines ...
Jan 20, 2022 · Thus, the order of basicity of aliphatic amines should be: primary > secondary > tertiary. Now I have a problem with the first line. Greater is the stability of the substituted ammonium cation, stronger should be the corresponding amine as a base.
organic chemistry - LogP of halogen derivatives of aromatics and ...
Nov 5, 2015 · Furthermore on aliphatic compounds, we observe this trend which confuses matters more.-Fluorine DECREASES logP slightly (by -0.17) on an aliphatic compound. The book doesn't give a reference as to which alpiphatic compound this is and which hydrogen is substituted, but oh well. -Chlorine increases logP (by 0.39) on the same aliphatic compound.
nmr spectroscopy - Why do aromatic hydrogen atoms have a …
In Nuclear magnetic resonance (H-NMR) spectroscopy, the chemical shift of aliphatic hydrogen atoms are very much closer to the 1.0 ppm than that of aromatic hydrogen atoms. Aromatic hydrogen atoms have a chemical shift value of about 7.0-9.0 ppm whereas the chemical shift value of aliphatic hydrogen atoms ranges between 2.0-3.5 ppm.
organic chemistry - How to transform an aliphatic primary amine …
May 23, 2016 · Could you suggest a reagent or procedure to transform an aliphatic primary amine to the corresponding nitro compound. I know this is a bit backwards of a request because the usual procedure is the reduction of nitro groups to their corresponding amine, but there is a need of its electron-withdrawing properties for a subsequent condensation to ...
General safety of aromatic vs. aliphatic hydrocarbon solvents
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Reason for the stronger acidic property of phenol than alcohol
In phenol, pulling the $\mathrm{p}_z$ electrons from the oxygen atom into the ring causes the hydrogen atom to be more partially positive than it is in aliphatic alcohols. This means it is much more easily lost from phenol than it is from aliphatic alcohols, so phenol has a stronger acidic property than ethanol.